A Study of adsorption of crystal violet dye from water using biochar derived from olive tree
Article Sidebar
Main Article Content
Abstract
Adsorption system is one of the most widely used chemical methods for removing dissolved pollutants from water, such as dyes. This system is characterized by its high efficiency and low cost, in addition high adsorption capacity of the adsorbent. In this study, local biochar derived from olive waste cake was used as an adsorbent for the removal of crystal violet from aqueous solutions. The adsorbent characterization study was performed using four-transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). Some factors affecting the adsorption rate were evaluated, such as contact time, initial dye concentrations, amount of biochar, and pH. The remaining dye concentrations in the solution after adsorption were analyzed using an ultraviolet-visible (UV-visible) spectrophotometer. The results obtained indicate that the best adsorption conditions were achieved at a contact time of 60 min, an initial dye concentration of 50 mg/L, a charcoal content of 0.3 gl. The maximum adsorption capacity for dye removal by biochar was found to be 8.93 mg/g.
Article Details
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
References
Gupta V. K., Carrott P. J. M., Carrott M. M. L. R., and Suhas (2009) Low-Cost Adsorbents: Growing Approach to Wastewater Treatment-A Review, Critical Reviews in Environmental Science and Technology 39: 783-842; Doi:10.1080/10643380801977610
Joshua O. Ighalo , Fredrick O. Omoarukhe, Victor E. Ojukwu , Kingsley O. Iwuozor, Chinenye Adaobi Igwegbe. (2022) Cost of adsorbent preparation and usage in wastewater treatment: A review, Cleaner Chemical Engineering 3: 100042. https://doi.org/10.1016/j.clce.2022.100042
مريم محمد الخيالي و ميمونة ابوبكر جبجي (2016 – 2017 ) إزالة صبغة الميثيلين الأزرق من المحاليل المائية بواسطة مسحوق حبيبات أكسيد السبينل النانوية المغناطيسية من نوع فيرايت الكوبلت المطعم بالموليبدينوم و المحضر بطريقة السو- جل، بحث تخرج مقدم لاستكمال متطلبات الحصول علي درجة الباكلوريوس ، قسم الكيمياء، كلية لعلوم، جامعة سبها- ليبيا.
Adegoke K. A., Bello O. S. (2015) Dye Sequestration Using Agricultural Wastes as Adsorbents, Water Resources and Industry, 12: 8–24. http://dx.doi.org/10.1016/j.wri.2015.09.002
Amit Bhatnagara, Mika Sillanpää (2010) Utilization of Agro-Industrial and Municipal Waste Materials as Potential Adsorbents for Water Treatment—A Review, Chemical Engineering Journal 157 : 277–296. Doi:10.1016/j.cej.2010.01.007.
Abhay Prakash Rawat, Vinay Kumar, and Devendra Pratap Singh (2019) A Combined Effect of Adsorption and Reduction Potential of Biochar Derived from Mentha Plant Waste on Removal of Methylene Blue Dye from Aqueous Solution, Separation Science and Technology: 1–15. https://doi.org/10.1080/01496395.2019.1580732
Sulyman M., Namiesnik J., Gierak A. (2017) Low-cost Adsorbents Derived from Agricultural By-products/Wastes for Enhancing Contaminant Uptakes from Wastewater: A Review, Pol. J. Environ. Stud. Vol. 26, No. 2: 479-510. Doi: 10.15244/pjoes/66769
الزطريني. (2021) دراسة إزالة ملوثات الماء بواسطة مخلفات عصر ثمار الزيتون المعالجة. بحث مقدم لاستكمال درجة الإجازة العليا الماجستير، قسم الكيمياء، كلية العلوم جامعة الزاوية- ليبيا.
Singh S. and Nain L. (2014) Microorganisms in the Conversion of Agricultural Wastes to Compost, Proc Indian Natn Sci Acad 80(2): 473-481.
Denga H, Lu J., Li G., Zhang G., Wang X. (2011) Adsorption of Methylene Blue on Adsorbent Materials Produced from Cotton Stalk, Chemical Engineering Journal 172: 326– 334. doi:10.1016/j.cej.2011.06.013.
Fuat Guzel , Hasan Sayg , Gulbahar Akkaya Sayg, Filiz Koyuncu. (2014) Decolorisation of Aqueous Crystal Violet Solution by a New Nanoporous Carbon: Equilibrium and Kinetic Approach, Journal of Industrial and Engineering Chemistry, 20, 3375-3386, 2014.
Ronsse F, Nachenius RW, Prins W. (2015) Chapter 11 Carbonization of biomass: Recent Advances in Thermo-Chemical Conversion of Biomass. 293-324. https://doi.org/10.1016/B978-0-444-63289-0.00011-9
Nadarajah K., Asharp T. & Jeganathan Y. (2024) Biochar from Waste Biomass, its Fundamentals, Engineering Aspects, and Potential Applications: An Overview, Water Science & Technology , 89(5). Doi: 10.2166/wst.2024.051
Aseel M. Aljeboree , Ayad F. Alkaima, Ammar H. Al-Dujaili. (2014) Adsorption Isotherm, Kinetic Modeling and Thermodynamics of Crystal Violet Dye on Coconut Husk-Based Activated Carbon, Desalination and Water Treatment, 1–12. Doi: 10.1080/19443994.2013.877854.
Langmuir I. (1918) The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinum, J. Am. Chem. Soc. 40: 1361–1403.
Freundlich H.M.F. (1906) Uber Die Adsorption in Losungen, Z. Phys. Chem. 57A: 385–470.
El-khamsa Guechi and Oualid Hamdaoui (2011) Sorption of Malachite Green from Aqueous Solution by Potato Peel: Kinetics and Equilibirum Modeling Using non-linear Anlysis Method, Arabian Journal of Chemistry; Doi:10.1016/j.arabjc.2011.05.011
Laura Bulgariu, Leticia Belén Escudero, Olugbenga Solomon Bello, Munawar Iqbal, Jan Nisar, Kayode Adesina Adegoke, Fadi Alakhras, Michael Kornaros, Ioannis Anastopoulos (2019) The utilization of leaf-based adsorbents for dyes removal: A review, Journal of Molecular Liquids 276: 728–747. https://doi.org/10.1016/j.molliq.2018.12.001
Deniz F. and Yildiz H. (2019) Bioremediation Potential of a Widespread Industrial Biowaste as Renewable and Sustainable Biosorbent for Synthetic Dye Pollution, International Journal of Phytoremediation 21(3): 259-267. https://doi.org/10.1080/15226514.2018.1524451
Maha A. Tony (2021) Low-cost Adsorbents for Environmental Pollution Control: A Concise Systematic Review from the Prospective of Principles, Mechanism and their Applications, Journal of Dispersion Science and Technology. https://doi.org/10.1080/01932691.2021.1878037
Mohamed Sulyman and Andrzej Gierak Green Environmental Approach for Adsorption of Hazardous Dye from Water Using Tree and Sea Plant Leaves (Dead L.), Acta Scientific Agriculture 4.2: 01-10.
Maraie AA. and Ibrahim HG. (2015) Biosorption of Copper (II) Ion from Wastewater onto Green Waste Tea: Isotherm and Kinetic Modeling Studies. Der Chemica Sinica 6.7:100-111.
نزار شعيب. (2023) استغلال نشارة الخشب في معالجة المياه الملوثة بصبغة المثيلين الأزرق. بحث مقدم لاستكمال درجة الإجازة العليا الماجستير، قسم هندسة وعلوم البيئة، الأكاديمية الليبية – ليبيا.
Mosoarca G., Vancea C., Popa S., Gheju M., Boran S. (2020) Syringa Vulgaris Leaves Powder a Novel Low-Cost Adsorbent for Methylene Blue Removal: Isotherms, Kinetics, Thermodynamic and Optimization by Taguchi Method, Scientific Reports 10: 17676. https://doi.org/10.1038/s41598-020-74819-x
Etim UJ., Umoren S.A., Eduo U.M. (2016) Coconut Coir Dust as a Low Cost Adsorbent for the Removal of Cationic Dye From Aqueous Solution, Journal of Saudi Chemical Society, 20: S67-S76. https://doi.org/10.1016/j.jscs.2012.09.014
Ferrero F. (2007) Dye Removal by Low Cost Adsorbents: Hazelnut Shells in Comparison with Wood Sawdust, Journal of Hazardous Materials 142: 144–152; Doi:10.1016/j.jhazmat.2006.07.072
سعاد نصر محمد عون (2017) استغلال مخلفات البن المطحون كمادة امتزازية في ازالة الاصباغ العضوية من الأوساط المائية. بحث مقدم لاستكمال متطلبات درجة لماجستير، قسم الكيمياء، الاكادمية الليبية – ليبيا.