دراسة تأثير مستخلص الكحولي و المائي لإوراق السدر على تثبيط تأكل الحديد المتوسط الكربون في 0.5 مولارى من محلول حمض الهيدروكلوريك.
محتوى المقالة الرئيسي
الملخص
الهدف من هذه الدراسة هو دراسة تأثير مثبط اورق السدر على تآكل الفولاذ المنخفض (الفولاذ المتوسط الكربون) في محلول 0.5 مولار من حمض الهيدروكلوريك (HCl) على مدى درجات حرارة 30 و 60 درجة مئوية. عن طريق قياسات فقدان الوزن. تم استخدام التحليل الكيميائي لتحديد تأثير إضافة حمض الهيدروكلوريك على تآكل وتثبيط تآكل الفولاذ الطري في 0.5 مولار من حمض الهيدروكلوريك (HCl) عند درجتي 30، 60 درجة مئوية في غياب ووجود المستخلصات المائية والكحولية لنبات السدر , تم تقييم كفاءة تثبيط التآكل باستخدام طريقة قياس فقدان الوزن. يُطلق على الطريقة القياسية لقياس فقدان الوزن للأسطوانات المعدنية المعرضة للبيئات المسببة للتآكل اسم اختبار التآكل بالغمر في المختبر. عند درجتي الحرارة 30 درجة مئوية أو 60 درجة مئوية، تم اكتشاف أن تأثير تركيز المثبط على معدل تآكل الفولاذ المنخفض يزداد مع تركيز المثبط. للعثور على نماذج مجموعات بيانات التوازن متساوي الحرارة الأكثر دقة للمثبط المستخدم، تم استخدام البيانات التجريبية. جميع الايزو الامتزاز المستخدم، مثل الايزوتيمكينولانجميور، يناسب النتائج، على الرغم من أن تطبيق مثبط مستخلص الكحول عند 60 درجة مئوية أظهر تحسنًا طفيفًا.
تفاصيل المقالة
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المراجع
. Odusote J. K., D. O. Owalude, O. Sunday Joseph, and R. A. Yahya, “Inhibition Efficiency of Moringa Oleifera Leaf Extract on the Corrosion of Reinforced Steel Bar in HCl Solution,” West Indian J. Eng., vol. 38, no. 2, pp. 64–70, 2015.
Khadom AA, Abd AN and Ahmed NA (2018) Xanthium strumarium leaves extracts as a friendly corrosion inhibitor of low carbon steel in hydrochloric acid: Kinetics and mathematical studies. South African Journal of Chemical Engineering, 25:13-21
B.Muller, Corrosion inhibition of aluminium and zinc pigments by saccharides.Corros.Sci. 44 (2002) 1583.
A.El-Hosary, R.M.Saleh, A.M.Sharns El Din, Corrosion inhibition by naturally occurring substances—I. The effect of Hibiscus subdariffa (karkade) extract on the dissolution of Al and Zn. Corros.Sci. 12 (1972) 897. 3. A.Y. El-Etre, Inhibition of aluminum corrosion using Opuntia extract, Corros. Sci. 45 (2003) 2485.
A.Y. El-Etre, Natural honey as corrosion inhibitor for metals and alloys. i. copper in neutral aqueous solution. Corros. Sci. 40 (1998) 1845.
A.Y. El-Etre, M. Abdallah, Natural honey as corrosion inhibitor for metals and alloys. II. C-steel in high saline water. Corros. Sci. 42 (2000) 731.
A.Y. El-Etre, Khillah extract as inhibitor for acid corrosion of SX 316 steel. Appl. Surf. Sci. 25 (2005) 8521.
A.Y. El-Etre, Inhibition of acid corrosion of aluminum using vanillin. Corros. Sci. 43 (2001) 1031.
A. Bouyanzer, B. Hammouti, A study of anti-corrosive effects of Artemisia oil on steel. Pigm. Res. Technol. 33 (2004) 287.
E.E.Oguzie, Inhibition of acid corrosion of mild steel by Telfariaoccidentalis. Pigm.Res.Technol.34 (2005)321.
M.G. Sethuraman, P. Bothi Raja, Corrosion inhibition of mild steel by Daturametel. Pigm. Res. Technol. 34 (2005) 327.
Prabhu D (2013) Studies of corrosion of aluminium and 6063 aluminium alloy in phosphoric acid medium. International Journal of Chem Tech Research, 5: 2690-2705
Yang, W.K., Chueh, Y.R., Cheng, Y.J., Siegenthaler, D., Pielage, J., Chien, C.T. (2019). Epidermis-Derived L1CAM Homolog Neuroglian Mediates Dendrite Enclosure and Blocks Heteroneuronal Dendrite Bundling. Curr. Biol. 29(9): 1445--1459.e3.
M. Librini , F. Robert , A. Lecante and C.Roos , Corros. Sci., 2011, 53 , 687 —695 ..
A. S. Fouda , S. Etaiw and W. Elnaggar , Int. J. Electrochem. Sci., 2014, 9 , 4866 —4883 .
L. Li , X. Zhang , j. Lei , J. He , S. Zhang and F. Pan , Corros. Sci., 2012, 63 , 2 . .
N. Odewunmi , S. Umoren and Z. Gasem , J. Ind. Eng. Chem., 2015, 21 , 239 .
M. Mageed , A. Sultan and H. Al- Sahlanee , J. Chem. Pharm. Res., 2013, 5 , 1297 .
L. Atia , R. Salghi , L. Bammou , L. h. Bazzi , B. Hammoutiand L. Bazzi , Acta Metall. Sin., 2012, 25 , 10 —18.
C. Sells , O. Benali , B. Tabti , L. Larabi and Y. Harek , J. Mater. Environ. Sci., 2012, 3 , 206 —219
A.Y.El-Etre, M.Abdallah, Z.E.El-Tantawy, ―Corrosion inhibit ion of some metals using lawsonia extract‖. Corros. Sci. 47(2) (2005) 385- 395. 12.O.K.Aboia, A.O. James, The effects Of Aloe vera extract on Corrosion and Kinetics of corrosio process of zinc in HCl Solution‖, Corros. Sci. 52(2) (2010) 661-664.
M.Lebrini, F.Robert, C.Roos, Inhibit ion effect of alkaloids extract from Annonasquamosa plant on the corrosion of C38 steel in normal HCl medium‖, Inter.J.Electrochem.Sci. 5(11) (2010) pp.1678- 1712.
R.Saratha, V.G.Vasudha, ―EmblicaOfficinalis (Indian Gooseberry) leaves extract as corrosion inhibitor for mild steel in 1 N HCl medium‖. E-Journal of Chemistry 7(3) (2010) pp.677-684.
Y.F.Barakat, A.M.Hassan, A.M Baraka, ―Corrosion inhibit ion of mild steel in aqueous solution containing HS by some naturally occurring substances‖. Materialwissenchaft und Werkstofftechnik 29(7) (1998) pp.365-370.
James A. O.andAkaranta O," Inhibition of corrosion of zinc in hydrochloric acid solution by red onion skin acetone extract".Res.J.Chem.Sci Vol. 1 (1) April (2011). 2
Abakedi OU. Inhibition of aluminium corrosion inhydrochloric acid solution by Stachytarpheta indica leaf extract. Journal of Scientific and Engineering Research 2016;3(3):105-110.
H. Ma, S. Chen, B. Yin, S. Zhao, X. Liu, Corros. Sci. 45 (2003) 867.
Hugel, G., Corrosion Inhibitors—Study of their Activity Mechanism, in 1st European Symposium on Corrosion Inhibitors, Ferrara, Italy, U. of Ferrara, 1960.
M. T. Saeed et al, Corrosion inhibition of mild steel in 1 M HCl by sweet melon peel
extract, Journal of King Saud University – Science 31, (2019), 1344–1351.
Raja, P.B., et al., Reviews on corrosion inhibitors: a short view. Chemical Engineering Communications, 2016. 203(9): p. 1145-1156.
Y.ELouadi, A.Bouyanze,L.Majiadi,J.Paolini,J.Desjobert, J.Costa, A.Chetouan, and B.Hammouti.Salvia offocinalis essential oil and the extract as green corrosion inhibitor mild steel in hydrochloric acid .journal of chemical and pharmaceutical research,2014,6(7),1401-1416.
Masouda Farhat,, Taha Abdullah, Faraj Mansour, Rbeeah Alsadiq” Studying the effect of Moringa inhibitor on the corrosion of mild steels in 0.5 M H2SO4 at temperatures 40 °C and 50 °C, Academy journal for Basic and Applied Sciences (AJBAS)Volume 4#3 December 2022.
Mohammed Suliman ,ohammed Alkilani , Taha Abdullah , Masouda Ali, The Effect of Methyle Carbazodithoate" Corrosion inhibitor on Corrosion Behaviour of Low Carbon Steels in Acid Solution at Different Temperatures. Journal of Pure & Applied Sciences ,www.Suj.sebhau.edu.ly ISSN 2521-9200 Received 16/04/2019 Revised 22/08/2019 Published online 25/11/2019.
Y. El ouadi, A. Bouyanze1, L. Majidi, J. Paolini, J. M. Desjobert, J. Costa, A. Chetouan, and B. Hammouti. Salvia officinalis Essential oil and the extract as green corrosion inhibitor o mild steel in hydrochloric acid. Journal of Chemical and Pharmaceutical Research, .2014, 6(7);1401 - 1416.
C. Natarajan, C.D Sheela and P.R Athappan. Synthesis and study of cobalt ( II ), nickel ( II ), copper ( II ) and zinc ( II ) complexes of 2-
formyl- and 2-acetyl-cyclohexanones. Indian J of Chemistry. 569–72(1990).
M. Sanchez and J. R. T.Aracona, J. Chil. Chem. Soc., 50 (1), 1(2005).
A.R.Patil, , K.J.Donde, , S.S.Raut, , V.R. Patil, and R.S. Lokhande, Synthesis, Characterization and BiologicalActivity of Mixed Ligand Co(II) Complexes of Schiff Base 2-Amino-4-nitrophenol-n-salicylidene with Some Amino Acids. Journal of Pharmacy Research, 4, 1413-1425(2012).
Fuertenau D.W. The adsorption of surfactants at solid / water interfaces in: Hair ML, editor. The chemistry of biosurafces, (New York. 1971) 143.
Ebenso, E. E, Eddy, N. O. and Odiongenyi, A. O. Corrosion inhibitive properties and adsorption behavior of ethanol extract of piper guinens is as a green corrosion inhibitor for mild steel in H 2 SO 4 . African Journal of Pure and applied chemistry, 2008, 11;107-115.
Rupesh Kushwah, Inhibition of Mild Steel Corrosion in 0.5 M H₂SO₄ Solution by Aspirin Drug, Dept. Of Chemistry, Govt. Dhar Polytechnic College, Dhar, M. P.(India), ISSN 2250-2459, (2014).